New sesquiterpene/quinones from two sponges of the genus Hyrtios
Salmoun, M.; Devijver, C.; Daloze, D.; Braekman, J.C.; Gomez, R.; de Kluijver, M.; Van Soest, R.W.M. (2000). New sesquiterpene/quinones from two sponges of the genus Hyrtios. J. Nat. Prod. 63(4): 452-456. https://dx.doi.org/10.1021/np9903346
In: Journal of Natural Products. American Chemical Society/American Society of Pharmacognosy: Washington DC. ISSN 0163-3864; e-ISSN 1520-6025, meer
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| Auteurs | | Top |
- Salmoun, M.
- Devijver, C.
- Daloze, D.
- Braekman, J.C.
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- Gomez, R.
- de Kluijver, M., meer
- Van Soest, R.W.M., meer
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| Abstract |
Two sponges of the genus Hyrtios have been found to contain new sesquiterpene/quinones identified by detailed spectroscopic analysis. Four new compounds with a 4,9-friedodrim-3-ene skeleton [hyrtiophenol (2), 5-epihyrtiophenol (3), 18-hydroxy-5-epihyrtiophenol (4), and 18-hydroxyhyrtiophenol (5)] were isolated from Hyrtios sp. (Seychelles Islands) along with isospongiaquinone (1). Moreover, the new compound 21-hydroxy-19-methoxyarenarone (8), which bears the 4,9-friedodrim-4(15)-ene skeleton, was isolated from Hyrtios tubulatus (Curaçao) along with arenarol (6) and 5-epiilimaquinone (7). Assignment of the 13C NMR signals of four types of 4,9-friedodrimene skeletons found in sponges is presented. |
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